Product ID:CITGARD 500 MOTOR OIL, SAE 20W-50, 22-350
MSDS Date:03/23/1995
FSC:9150
NIIN:00N078099
MSDS Number: CFHHZ

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 918-495-4700;800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 7X110

CITGO PETROLEUM CORP

3758 TULSA, OK 74102 US

Telephone: 918-495-5933

Cage: 7X110

REFINED PETROLEUM OIL CONTAINING ONE OR MORE OF INGREDIENTS

RTECS: 9999999ZZ

Fraction By Weight: >75%

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY

CAS: 64742-65-0

RTECS: PY8038501

OSHA PEL N/K

ACGIH TLV: N/K

HYDROTREATMENT); (SOLVENT DEWAXED, HEAVY PARAFFINIC

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM)

CAS: 64742-62-7

OSHA PEL N/K

ACGIH TLV: N/K

SOLVENT REFINED RESIDUM

CAS: 64742-01-4

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, SOLV-REFINED (SEVERE)

CAS: 64741-88-4

RTECS: PY8040501

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, SOLV-REFINED (SEVERE)

CAS: 64741-89-5

RTECS: PY8041501

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE)

CAS: 64742-54-7

RTECS: PY8035501

OSHA PEL N/K

ACGIH TLV: N/K

SOLVENT REFINED, HYDROTREATED LIGHT PARAFFINIC DISTILLATE;

CAS: 64742-55-8

RTECS: PY8036500

OSHA PEL N/K

ACGIH TLV: N/K

SOLVENT REFINED HYDROTREATED RESIDUAL OIL; (HYDROTREATED

CAS: 64742-57-0

OSHA PEL N/K

ACGIH TLV: N/K

SEVERELY HYDROTREATED HYDROCARBON OIL; (HYDROTREATED

CAS: 72623-87-1

OSHA PEL N/K

ACGIH TLV: N/K

HIGHLY REFINED BASE OIL; (HYDROTREATED HIGH-VISCOSITY

CAS: 72623-85-9

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL; (HYDROTREATED BRIGHT STOCK LUBRICATING OIL)

CAS: 72623-83-7

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATE, CATLYTIC DEWAXED (MILD),

CAS: 64742-70-7

RTECS: PY8045500

OSHA PEL N/K

ACGIH TLV: N/K

DETERGENT INHIBITOR AND ANTI-OXIDANT (CONTAINING INGREDIENT

RTECS: 9999999ZZ

Fraction By Weight: <20%

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC

CAS: 68649-42-3

Fraction By Weight: <2.0%

OSHA PEL N/K

ACGIH TLV: N/K

VI IMPROVER (TYPE NOT SPECIFIED)

Fraction By Weight: 0-15%

OSHA PEL N/K

ACGIH TLV: N/K

POUR POINT DEPRESSANT

Fraction By Weight: 0-1%

OSHA PEL N/K

ACGIH TLV: N/K

ZERO. FOR INGEST OF LG QTYS EMESIS OR LAVAGE MAY BE

RTECS: 9999999ZZ

SURGICAL DEBRIDEMENT. IF NOT FAMILIAR WITH

RTECS: 9999999ZZ

& REGS. CONSIDER THE CHARACTS OF USED PROD

RTECS: 9999999ZZ

ANIMALS. AFTER DRAINING OIL, WASH SKIN

RTECS: 9999999ZZ

PROD RESIDUE WHICH COULD INCL FLAM/EXPLO VAPS.

RTECS: 9999999ZZ

RECONDITIONING, RECLAIMING, RECYCLING OR DISPOSING

RTECS: 9999999ZZ

MANDATED STANDARDS AS EVALUATED BY DESIGNATED

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: LOW RISK OF INHAL AT
AMBIENT TEMPS. MISTS/FUMES MAY CAUSE DROW, DIZZ, HDCH, NAUS OR RESP
IRRIT. MISTS ABOVE TLV MAY CAUSE CHEM PNEUMIT. SKIN/EYE CNTCT:
PRACTICALLY NON-IRRITANT. INGEST: LOW TOXICITY. ON INGEST OF LG
QTYS, SLIGHT GI DISCOMFORT, DIARR & HDCH MAY OCCUR. SM DOSES MAY
PRDCE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: IRRIT & DIARR. INJECTION:
SUBCUTANEOUS OR INTRAMUSCULAR INJECTION MAY CAUSE IRRIT, ERYTHEMA,
EDEMA. CHRONIC: PRLNGD &/OR FREQUENT CNTCT MAY CAUSE DRYING,
CRACKING (DERM) OR FOLLICULITIS & MA Y CAUSE SLIGHT IRRIT.
TOXICITY: PRACTICALLY NON-TOXIC. APPROX LETHAL ORAL DOSE FOR 150LB
HUMAN ADULT IS ABOUT (SUPDAT)
Medical Cond Aggravated by Exposure:NONE.

First Aid:INHAL: REMOVE FROM EXPOS TO INCIDENTAL FUMES & PROVIDE RESP
SUPPORT IF NEC. SEEK MED AID. SKIN: WASH W/SOAP & WATER. DO NOT
WEAR HEAVILY CONTAMD CLTHG BEFORE LAUNDERING. EYES: FLUSH W/LG VOLS
OF WATER FOR AT LST 15 MIN. SEEK MD IF ANY COMPLICATIONS ARISE.
INGEST: INDUCE VOMIT. SEEK MED AID. INJECTION: SUBCUTANEOUS
INJECTION IS MED EMER. SEEK MED AID IMMED. NOTES TO MD: FOLLOWING
INGEST, (SUPDAT)

Flash Point Method:PMCC
Flash Point:>356F,>180C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING.

Spill Release Procedures:REMOVE HEAT/IGNIT SOURCES. PROVIDE ADEQ VENT.
SM SPILL:TAKE UP W/NONCOMBUST ABSORB IE, FULLERS EARTH/SAND. PLACE
INTO CNTNR FOR LATER DISP. LG SPILLS:CNTN SPILL IN EARTHEN DIKES
FOR LATER RECOVERY. CT L IGNIT SOURCES AROUND AREA. RPT AS REQD TO
AUTHS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD & AWAY FROM
HEAT & FLAME. AVOID PRLNGD SKIN CNTCT W/USED MOTOR OILS; CONTINUOUS
CNTCT HAS CAUSED SKIN CANCER IN LAB (ING 22)
Other Precautions:PROT MEASURES DURING REPAIR & MAINT OF CONTAMD
EQUIP:REFER TO SPEC PROT INFO SECTION. WASH EXPOS SKIN THOROUGHLY
W/SOAP & WATER. REMOVE SOILED CLTHG. USE POLYMER GLOVES IF
EXTENDED, DIRECT CNTCT EXPEC TED. AVOID PRNGD CNTCT W/USED OIL.

Respiratory Protection:IF HIGH VAPOR CONCENTRATION IS EXPECTED, USE
NIOSH APPROVED RESPIRATOR APPROVED FOR ORGANIC VAPORS.
Ventilation:USE IN WELL VENTD AREA. IN CONFINED SPACE, MECH VENT MAY BE
REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (ING 25)
Protective Gloves:OIL IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR BODY-COVERING WORK CLOTHES TO AVOID PROLONGED/REPEATED
EXPOSURE.
Work Hygienic Practices:LAUNDER SOILED WORK CLOTHES BEFORE REUSE.
Supplemental Safety and Health
SPEC GRAV: 0.87-0.91 (H*2O=1). FL PT/METH: >399F,>204C/COC. EFTS OF
OVEREXP: 1 PINT TO 1 QUART. CAUTION: AVOID PRLNGD SKIN CNTCT W/USED
MOTOR OILS. CONTINUOUS CNTCT W/USED OIL HAS CAUSED SKIN CANCER I N
LAB ANIMALS. FIRST AID PROC: AT SAYBOLT VISCOSITY OF >400 AT 100F,
RISK OF ASPIR INTO LUNGS IS PRACTICALLY (ING 19)

Boiling Pt:B.P. Text:>680F,>360C
Vapor Pres:<1X10/3
Vapor Density:>1
Spec Gravity:SUPDAT
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER TO DARK AMBER LIQUID; SLIGHT PETROLEUM ODOR.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON DIOXIDE (CARBON MONOXIDE UNDER
INCOMPLETE COMBUSTION). TRACES OF OXIDES OF S, ZN AND P.

Waste Disposal Methods:IT IS USER'S RESPONSIBILITY TO DETERM IF MATL IS
HAZ WASTE AT TIME OF DISP. USED OILS MAY BE SUITABLE FOR PROCESSING
BY APPRVD RECYCLING FACILITY. USE OF ANY DISP/RECYCLING METHS ARE
SUBJECT TO COMPLI ANCE W/ALL APPLIC FED, STATE & LOCAL LAWS (ING
21)

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